CYCLIC VOLTAMMETRIC STUDIES FOR DIFFERENT SUBSTITUTED BENZILS

Authors

  • Nithya G vels university, Pallavaram,Chennai
  • Charles C Kanakam
  • Sudha R

Abstract

ABSTRACT
The electroreduction of different substituted benzils was synthesized and studied in alcoholic and alkaline medium by cyclic voltammetry. In alkaline
solutions, the reduction occurs in two reversible one-electron steps producing the anion radical and the dianion. In the presence of alcohol, the
first reduction is unaffected and the second reduction wave becomes irreversible and is shifted toward positive potentials, following qualitatively
the criteria for a rapid reaction of the dianion with the proton donor. The protonation can occur through the radical anion since it is not possible to
observe the first step of the reaction to the radical anion.
Keywords: Cyclic voltammetric studies, Synthesized benzils, Electroanalysis.

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References

REFERENCES

Hooka J, Hinks D, Harold Freoman color. Technol 2002;118(1):32.

Boblut W, John P. J Org Chem 1980;45:1978.

Stephan NF, Carl RK, David BJ. J Org Chem 1980;45:2116.

Michael PJ, Meta and J Thomas J Am Chem Soc 1980;102:1289.

Kissinger PT, Heineman WR. J Chem Educ 1983;60:70.

Van Benschoten JJ, Lewis JY, Heineman WR, Kissinger PT . J

Chem

Educ 1983;60: 772.

Baldwin RP, Ravichandran Johnson RK. J Chem Educ 1984;61:820.

Ibanew JG, Gonzlez I, Cardenas MC. J Chem Educ 1988;65:173.

Kissinger PT, Heineman WR. Laboratory Techniques

in

Electroanalytical Techniques. New York: Dekker; 1985.

Published

01-05-2016

How to Cite

G, N., C. C. Kanakam, and S. R. “CYCLIC VOLTAMMETRIC STUDIES FOR DIFFERENT SUBSTITUTED BENZILS”. Asian Journal of Pharmaceutical and Clinical Research, vol. 9, no. 3, May 2016, pp. 82-84, https://mail.innovareacademics.in/journals/index.php/ajpcr/article/view/10130.

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